Search results for "powder metallurgy"

Synthesis of FeAl Hetero-Nanostructured Bulk Parts via Spark Plasma Sintering of Milled Powder

2006

AbstractSpark plasma sintering (SPS) has been used in order to introduce nanocrystalline grains within fully dense FeAl consolidated parts. Hetero-nanostructured parts, consisting of nano, ultrafine and micrometric grains, have been successfully processed when milled - Y2O3 reinforced - FeAl powder was used. The large temperature differences that are spontaneously generated during the SPS process as well as the use of milled powder account for the formation of such interesting structures. The grain size distribution - that is suggested to be very potent to improve both strength and ductility - could be significantly modified by a proper selection of sintering temperature and holding time.

Mechanically Activated SHS Reaction in the Fe-Al System: In Situ Time Resolved Diffraction Using Synchrotron Radiation

1998

The Mechanical Activation Self propagating High temperature Synthesis (M.A.S.H.S.) processing is a new way to produce nanocrystalline iron aluminide intermetallic compounds. This process is maily the combination of two steps ; in the one hand, a mechanical activation where the Fe - Al powder mixture was milled during a short time at given energy and frequency of shocks and in the other hand, a Self propagating High temperature Synthesis (S.H.S.) reaction, for which the exothermicity of the Fe + Al reaction is used. This fast propagated MASHS reaction has been in -situ investigated using the Time Resolved X - Ray Diffraction (TRXRD) using a X - ray synchrotron beam and an infrared thermograp…

Determination of transport and kinetic properties in self-propagating high-temperature synthesis

2007

International audience; Exothermic reactions in solid powders are analyzed using the usual macroscopic modeling based on the heat transfer equation coupled to an Arrhenius type of dynamics. This problem have important applications in the synthesis of intermetallics and ceramic materials which occur when a high temperature reaction wave propagates throughout the system. Understanding the mechanism of such processes are thus crucial in mastering real laboratory experiments. We first analyze the model, both theoretically and numerically, for a set of representative parameters. We then use traditional data analyses procedures to estimate from the temperature profiles the same set of representat…

Combustion synthesis of MoSi2 and MoSi2–Mo5Si3 composites: Multilayer modeling and control of the microstructure

2010

International audience; In this work, we present a multilayer modeling for the formation of molybdenum silicides in the exothermic reaction between Mo and Si under the influence of a temperature pulse. The heating rate can either be a well-controlled ramp or be generated spontaneously by the propagation of a combustion synthesis front. The model addresses the specific situation above the melting point of silicon and describes the solid–liquid reaction taking place in a single representative particle of molybdenum surrounded by the melt of silicon. We obtain a set of kinetic equations for the propagation of the interfaces between the different layers (Mo/Mo5Si3 and Mo5Si3/MoSi2) in the solid…

Experimental investigation and multi-scale modelling of the behavior of mechanically activated metallic powders : from binary systems to High Entropy…

2021

Generally, metal alloys consist of a main element associated with other elements present in smaller quantities such as iron, nickel, aluminum or copper alloys. The precise composition of an alloy is adjusted according to the required performance: high temperature behavior, corrosion resistance, mechanical properties, durability ... In 2004, a Taiwanese scientist, JW Yeh, had the idea of making an alloy base of several elements, at least 5, whose composition in the alloy varies between 5% and 30% at. Yeh invented the high entropy alloy (HEA). Mixed on a microscopic scale, the metals form a remarkably stable solid solution. The explanation is thermodynamic. An alloy is all the more stable as …

Correlation between milling parameters and microstructure characteristics of nanocrystalline copper powder prepared via a high energy planetary ball …

2007

The microstructure evolution of Cu-nanostructured powders versus the ball milling conditions was investigated by whole peak profile powder pattern modeling method. This method allows defining in some approach the characteristics of as-milled Cu powder microstructure in terms of crystallite size, type and density of dislocations and twin faults density. It is shown that the change of microstructure characteristics of as-milled Cu powder versus the ball milling conditions (under constant time of the ball milling) depend on only some energy parameters of the milling, for example, average size of crystallite is uniquely defined by energy of the shock, whereas the portion of edge and screw compo…

Thermal-electrical-mechanical simulation of the nickel densification by Spark Plasma Sintering. Comparison with experiments

2016

Abstract Spark Plasma Sintering is a non-conventional process of the powder metallurgy field which uses a high electrical current to rapidly produce fully dense materials. In the present paper, a thermal-electrical-mechanical model developed on ABAQUS Software is proposed to simulate the densification of a nickel disk. A compaction model, studied in [Wolff, C., Mercier, S., Couque, H., Molinari, A., 2012. Modeling of conventional hot compaction and spark plasma sintering based on modified micromechanical models of porous materials. Mechanics of Materials 49 (0), 72–91. URL http://www.sciencedirect.com/science/article/pii/S0167663611002195 ], has been used to reproduce the densification of t…

From nanostructured powders to dense nanostructured materials: Mechanically activated powder metallurgy

2003

Powder metallurgy processing and deformation characteristics of bulk multimodal nickel

2014

cited By 7; International audience; Spark plasma sintering was used to process bulk nickel samples from a blend of three powder types. The resulting multimodal microstructure was made of coarse (average size ∼ 135 μm) spherical microcrystalline entities (the core) surrounded by a fine-grained matrix (average grain size ∼ 1.5 μm) or a thick rim (the shell) distinguishable from the matrix. Tensile tests revealed yield strength of ∼ 470 MPa that was accompanied by limited ductility (∼ 2.8% plastic strain). Microstructure observation after testing showed debonding at interfaces between the matrix and the coarse entities, but in many instances, shallow dimples within the rim were observed indica…

Synthesis of niobium aluminides using mechanically activated self-propagating high-temperature synthesis and mechanically activated annealing process

1999

The mechanically activated self-propagating high-temperature synthesis (MASHS) technique and the mechanically activated annealing process (M2AP) were used to produce NbAl3 intermetallic compound. The MASHS process results from the combination of two steps: first, a mechanical activation of the Nb 3Al powders mixture; second, a self-propagating high-temperature synthesis (SHS). The M2AP process also results from the combination of two steps: the first is the same; the second consists of the annealing of as-milled powders. Based on X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDXS), the as-milled powders, MASHS, and M2AP end-pr…